Asymmetric Catalysis mediated by transition-metals

Asymmetric addition and cycloaddition reactions. Novel dipoles and dipolarophiles in 1,3-dipolar cycloadditions. Asymmetric synthesis of pyrrolidines and related heterocycles.

Alkenylarenes as Dipolarophiles in Catalytic Asymmetric 1,3-Dipolar Cycloaddition of Azomethine Ylides

Ana Pascual-Escudero, Abel de Cózar, Fernando P. Cossío, Javier Adrio, Juan C. Carretero

pub192Angew. Chem. Int. Ed. 2016, 55, 15334-15338

Catalytic Asymmetric Synthesis of Bicycloprolines by 1,3-Dipolar Cycloaddition/Intramolecular Alkylation Strategy

Enrique Arpa, María González Esguevillas, Ana Pascual Escudero, Javier Adrio, Juan C. Carretero


J. Org. Chem. 2016, 81, 6128-6135

Stereoselective Ag-Catalyzed 1,3-Dipolar Cycloaddition of Activated Trifluoromethyl Substituted Azomethine Ylides

Alberto Ponce, Inés Alonso, Javier Adrio, Juan C. Carretero


Chem. Eur. J. 2016, 22, 4952-4959

 Novel strategies for selectivity control in metal-catalysis oriented to organic synthesis

Development of new directing groups in metal-catalyzed reactions. C(sp2)-H y C(sp3)-H functionalization reactions mediated by transition metals in key starting materials. Development of synthetic applications

Palladium-Catalyzed Carbonylative Cyclization of Amines via γ-C(sp3)-H Activation: Late Stage Diversification of Amino Acids and Peptides

Elier Hernando, Julia Villalva, Angel Manu Martínez, Inés Alonso, Nuria Rodríguez, Ramón Gomez Arrayás, Juan C. Carretero


ACS Catal. 2016, 6, 6868-6882

Palladium-Catalyzed Remote ortho-C-H Alkenylation of Aryl Alkyl Sulfones: Access to Densely Functionalized Indane Derivatives

Pablo Domingo Legarda, Alfonso García-Rubia, Ramón Gómez Arrayás, Juan C. Carretero


Adv. Synth. Catal. 2016, 358, 1065-1072

Rh(I)/Rh(III) Catalyst-Controlled Divergent Aryl/Heteroaryl C-H Bond Functionalization of Picolinamides with Alkynes

Ángel Manu Martínez, Javier Echavarren, Inés Alonso, Nuria Rodríguez, Ramón Gómez Arrayás, Juan C. Carretero


Chem. Sci. 2015, 6, 5802-5814

Regioselective addition and cycloaddition reactions to C-C and C-X multiple bonds catalyzed by transition metals 

Borylation and silylation reactions of unsaturated systems. Activation of imines, alkenes and alkynes. Pauson-Khand reaction

Cu-Catalyzed Silylation of Alkynes: A Traceless 2-Pyridylsulfonyl Controller Allows Access to Either Regioisomer on Demand

Alfonso García-Rubia, Jose A. Romero-Revilla, Pablo Mauleón, Ramón Gómez-Arrayás and Juan C. Carretero


J. Am. Chem. Soc.  2015, 137, 6857-6865

Formal Regiocontrolled Hydroboration/Allylic Alkylation of Terminal Alkynes via Borylation/Allylic Alkylation of Terminal Alkynes

Abraham L. Moure, Pablo Mauleón, Ramón Gómez Arrayás, Juan C. Carretero


Org. Lett. 2013, 15, 2054-2057

Regiocontrolled Cu-Catalyzed Borylation of Propargylic Functionalized Internal Alkynes

Abraham L. Moure, Ramón Gómez Arrayás, Diego Cárdenas, Inés Alonso, Juan C. Carretero


J. Am. Chem. Soc. 2012, 134, 7219-7222



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